BAS ASTM D 4815:2025

1.1 This test method covers the determination of ethers and alcohols in gasolines by gas chromatography. Specific compounds determined are methyl tert-butylether (MTBE), ethyl tert-butylether (ETBE), tert-amylmethylether (TAME), diisopropylether (DIPE), methanol, ethanol, isopropanol, n-propanol, isobutanol, tert-butanol, sec-butanol, n-butanol, and tert-pentanol (tert-amylalcohol). 1.2 Individual ethers are determined from 0.20 % to 20.0 % by mass. Individual alcohols are determined from 0.20 % to 12.0 % by mass. Equations used to convert to mass percent oxygen and to volume percent of individual compounds are provided. At concentrations <0.20 % by mass, it is possible that hydrocarbons may interfere with several ethers and alcohols. The reporting limit of 0.20 % by mass was tested for gasolines containing a maximum of 10 % by volume olefins. It may be possible that for gasolines containing >10 % by volume olefins, the interference may be >0.20 % by mass. Annex A1 gives a chromatogram showing the interference observed with a gasoline containing 10 % by volume olefins.